إدارة سلامة الأصول

Hydrogen Blistering

تَقَرُّح الهَيْدْرُوجِين: تَهْدِيدٌ صَامِتٌ لِبُنْيَةِ نَفْطِ وَغَازِ

في بيئاتِ القَسَاوَةِ لِاسْتِخْرَاجِ وَتَصْوِيَةِ النَّفْطِ وَالغَازِ، تُعَانِي الفُلْزَاتُ مِن هَجُومٍ مُسْتَمْرٍّ. وَأَحَدُ أَكْثَرِ التَّهْدِيدَاتِ خِفْيًا الَّتِي تُوَاجِهُهَا تَأْتِي مِنَ الهَيْدْرُوجِين، وَهُوَ عُنْصُرٌ يَظْهَرُ بِسَطَاحَةٍ، لَكِنَّهُ يُمْكِنُ أَنْ يُسَبِّبَ أَضْرَارًا كَثِيرَةً عَبْرَ ظَاهِرَةٍ تُعْرَفُ بِاسْمِ **تَقَرُّحِ الهَيْدْرُوجِين**.

**مَا هُوَ تَقَرُّحِ الهَيْدْرُوجِين؟**

تَقَرُّحِ الهَيْدْرُوجِين هُوَ صُورَةٌ مِنْ تَشَقُّقِ الهَيْدْرُوجِين، وَهِيَ عَمَلِيَّةٌ يَدْخُلُ فِيهَا ذَرَّاتُ الهَيْدْرُوجِينَ هَيْكَلَ الفُلْزِ الْبَلُّورِيّ. وَيُؤَدِّي هَذَا التَّغَلُّلُ إِلَى تَكَوُّنِ **فُجَوَاتٍ** تُعْرَفُ غَالِبًا بِاسْمِ التَّقَرُّحَاتِ، تَحْتَ سَطْحِ الفُلْزِ فَقَطْ. وَيُمْكِنُ أَنْ تَنْمُوَ هَذِهِ الفُجَوَاتُ بِمُرُورِ الْوَقْتِ، مُؤَدِّيًا إِلَى **تَوَرُّمٍ** وَتَشَوُّهَاتٍ فِي سَطْحِ الفُلْزِ.

**كَيْفَ يَحْدُثُ؟**

يُمْكِنُ أَنْ يَدْخُلَ الهَيْدْرُوجِينُ الفُلْزَ بِطُرُقٍ عِدَّةٍ:

  • **التَّفَاعُلَاتُ الكِهْرُوكِيمِيَائِيَّةُ:** خِلالَ عَمَلِيَّاتِ التَّآكُلِ، يُمْكِنُ أَنْ تُوَلَّدَ أَيُونَاتُ الهَيْدْرُوجِينَ وَتُمتَصَّ فِي الفُلْزِ.
  • **بِيئَاتُ الهَيْدْرُوجِينِ ذَاتِ الضَّغْطِ العَالِي:** فِي عَمَلِيَّاتِ النَّفْطِ وَالغَازِ، يُمْكِنُ أَنْ يَذُوبَ غَازُ الهَيْدْرُوجِينِ ذُو الضَّغْطِ العَالِي فِي الفُلْزِ.
  • **اللَّحَامُ:** يُمْكِنُ أَنْ تُدْخِلَ عَمَلِيَّةُ اللَّحَامِ هَيْدْرُوجِينًا فِي الفُلْزِ، وَلَا سِيَّمَا إِذَا تَمَّ تَطْبِيقُ إِجْرَاءَاتٍ غَيْرِ صَحِيحَةٍ.

**لِمَ هُوَ مُهِمٌّ لِنَفْطِ وَغَازِ؟**

يُشَكِّلُ تَقَرُّحِ الهَيْدْرُوجِينِ مُخَاطِرَ كَبِيرَةً عَلَى بُنْيَةِ نَفْطِ وَغَازِ:

  • **انْخِفَاضُ الْقُوَّةِ:** يُضَعِّفُ وَجُودُ التَّقَرُّحَاتِ الفُلْزَ، مُجْعِلًا إِيَّاهُ أَكْثَرَ عُرْضَةً لِلْفَشَلِ تَحْتَ الضَّغْطِ.
  • **التَّسَرُّبَاتُ وَالْانْهِيَارَاتُ:** يُمْكِنُ أَنْ يُضَعِّفَ التَّقَرُّحَاتُ أَنَابِيبَ النَّقْلِ وَخَزَّانَاتِ التَّخْزِينِ وَالْمُعَدَّاتِ الْأُخْرَى، مُؤَدِّيًا إِلَى التَّسَرُّبَاتِ وَالْانْهِيَارَاتِ، مُشَكِّلًا مَخَاطِرَ بِئِيَّةٍ وَأَمْنِيَّةٍ.
  • **الْفَشَلُ الكَارِثِي:** فِي الْحَالَاتِ الشَّدِيدَةِ، يُمْكِنُ أَنْ يُسَبِّبَ تَقَرُّحِ الهَيْدْرُوجِينِ فَشَلًا كَارِثِيًّا، مُؤَدِّيًا إِلَى تَوَقُّفٍ كَبِيرٍ فِي الْعَمَلِ وَخَسَائِرَ إِقْتِصَادِيَّةٍ كَثِيرَةٍ.

**مَنْعُ تَقَرُّحِ الهَيْدْرُوجِين**

يَتَطَلَّبُ مَنْعُ تَقَرُّحِ الهَيْدْرُوجِينِ نَهْجًا مُتَعَدِّدَ الْأَطْرَافِ:

  • **اخْتِيَارُ الْمَادَّةِ:** يُمْكِنُ لِاخْتِيَارِ مَوَادَّ مُقَاوِمَةِ الهَيْدْرُوجِينَ، مِثْلَ فُلَاذَاتِ الْكْرُومِ - نِكِلِ الْقَابِلَةِ لِلْتَّأْكُلِ، أَنْ يُخَفِّضَ الْمُخَاطِرَ بِشَكْلٍ كَبِيرٍ.
  • **تَحْسِينُ الْعَمَلِيَّةِ:** يُمْكِنُ لِلْتَّحَكُّمِ الدَّقِيقِ فِي مَعَايِيرِ اللَّحَامِ وَالْعَمَلِيَّاتِ الْأُخْرَى أَنْ يُخَفِّضَ مِنْ دُخُولِ الهَيْدْرُوجِينِ فِي الفُلْزِ.
  • **إِزَالَةُ الضَّغْطِ:** يُمْكِنُ اسْتِخْدَامُ مُعَالَجَةِ الْحَرَارَةِ لِإِزَالَةِ الضَّغُوطِ الْدَاخِلِيَّةِ الَّتِي تُمْكِنُ أَنْ تُسَهِّلَ تَقَرُّحِ الهَيْدْرُوجِينَ.
  • **الْفَحْصُ الْدَوْرِي:** يُسَاعِدُ الْفَحْصُ الْدَوْرِيُّ فِي كَشْفِ وَجُودِ التَّقَرُّحَاتِ قَبْلَ أَنْ تُصْبِحَ مُشْكِلَةً جِدِّيَّةً.

**الْخُلَاصَةُ:**

يَشَكِّلُ تَقَرُّحِ الهَيْدْرُوجِينِ تَهْدِيدًا جِدِّيًّا لِبُنْيَةِ نَفْطِ وَغَازِ. بِفَهْمِ آَلِيَّاتِ هَذِهِ الظَّاهِرَةِ وَتَطْبِيقِ اسْتِرَاتِجِيَّاتِ مَنْعٍ مُنَاسِبَةٍ، يُمْكِنُ لِلصَّنَاعَةِ أَنْ تُخَفِّضَ مِنْ هَذِهِ الْمُخَاطِرَةِ وَتُؤَمِّنُ سَلَامَةَ وَعَدَدِ عَمَلِيَّاتِهَا.


Test Your Knowledge

Quiz: Hydrogen Blistering

Instructions: Choose the best answer for each question.

1. What is hydrogen blistering?

a) A type of corrosion that forms on the surface of metal. b) A form of hydrogen embrittlement where hydrogen atoms infiltrate metal and create cavities. c) A process where hydrogen gas reacts with metal to form a brittle compound. d) A type of surface coating used to protect metal from corrosion.

Answer

b) A form of hydrogen embrittlement where hydrogen atoms infiltrate metal and create cavities.

2. Which of the following is NOT a way hydrogen can enter metal?

a) Electrochemical reactions during corrosion. b) High-pressure hydrogen environments. c) Mechanical stress on the metal. d) Welding processes.

Answer

c) Mechanical stress on the metal.

3. What is a major consequence of hydrogen blistering in oil & gas infrastructure?

a) Increased metal strength. b) Decreased metal conductivity. c) Reduced metal strength and potential leaks. d) Enhanced metal resistance to corrosion.

Answer

c) Reduced metal strength and potential leaks.

4. Which of the following is a preventative measure against hydrogen blistering?

a) Using only low-grade steel for construction. b) Applying a protective coating to the metal surface. c) Selecting hydrogen-resistant materials. d) Increasing the pressure of hydrogen gas in the environment.

Answer

c) Selecting hydrogen-resistant materials.

5. What is the importance of regular inspections in preventing hydrogen blistering?

a) They help to detect leaks in pipelines and storage tanks. b) They help to identify the presence of blisters before they become a serious problem. c) They help to ensure that the metal is properly coated. d) They help to determine the amount of hydrogen present in the environment.

Answer

b) They help to identify the presence of blisters before they become a serious problem.

Exercise: Hydrogen Blistering Case Study

Scenario: A pipeline carrying high-pressure hydrogen gas has experienced a significant leak. Upon investigation, it was discovered that the pipeline was made of a standard carbon steel and displayed numerous hydrogen blisters on its surface.

Task:

  1. Identify at least three contributing factors that could have led to the development of hydrogen blisters in this pipeline.
  2. Suggest two potential preventative measures that could have been implemented to reduce the risk of hydrogen blistering in this case.
  3. Explain how these preventative measures would have addressed the contributing factors you identified.

Exercice Correction

**1. Contributing Factors:**
* **Material Selection:** The use of standard carbon steel, which is not inherently resistant to hydrogen embrittlement, increased the susceptibility to blistering. * **High-Pressure Hydrogen Environment:** The pipeline was carrying high-pressure hydrogen gas, which significantly increased the likelihood of hydrogen dissolving into the metal and forming blisters. * **Welding Procedures:** Improper welding procedures during pipeline construction could have introduced hydrogen into the metal, contributing to the formation of blisters. **2. Preventative Measures:**
* **Material Selection:** Using a hydrogen-resistant material, such as austenitic stainless steel, would have significantly reduced the risk of hydrogen blistering. * **Stress Relief:** Implementing stress relief heat treatment during the construction process would have reduced internal stresses in the metal, mitigating the potential for hydrogen embrittlement. **3. Explanation:**
* **Material Selection:** By selecting a hydrogen-resistant material, the susceptibility to hydrogen ingress and subsequent blister formation would have been greatly reduced. * **Stress Relief:** Stress relief heat treatment would have reduced internal stresses that can act as trapping sites for hydrogen atoms, decreasing the likelihood of blister formation.


Books

  • "Hydrogen Embrittlement of Metals" by J.P. Hirth (1980) - Comprehensive overview of hydrogen embrittlement, including a chapter on blistering.
  • "Corrosion Engineering: Principles and Applications" by D.A. Jones (2016) - Covers various types of corrosion, including hydrogen-induced cracking and blistering.
  • "Materials Selection and Design" by M.F. Ashby (2011) - Discusses material selection for various applications, including consideration of hydrogen embrittlement resistance.

Articles

  • "Hydrogen Blistering in Oil and Gas Industry" by S.P. Somasundaran (2019) - Focuses on hydrogen blistering in specific applications within oil and gas.
  • "Hydrogen Embrittlement of Steels: A Review" by R.P. Gangloff (1986) - A classic review article summarizing the different aspects of hydrogen embrittlement.
  • "Hydrogen Induced Cracking and Blistering in Oil and Gas Pipelines: A Review" by A.K. Dutta (2015) - In-depth review of hydrogen-related issues in pipelines.

Online Resources

  • ASM International (ASM International): https://www.asminternational.org/ - A leading source for materials science and engineering information, including articles and resources on hydrogen embrittlement.
  • NACE International (NACE): https://www.nace.org/ - A non-profit organization dedicated to corrosion control, providing resources on various types of corrosion, including hydrogen blistering.
  • Corrosionpedia: https://www.corrosionpedia.com/ - A comprehensive online encyclopedia of corrosion-related information, including articles and tutorials on hydrogen embrittlement and blistering.

Search Tips

  • "Hydrogen blistering oil and gas": This search will bring up relevant articles and resources on hydrogen blistering in the oil and gas industry.
  • "Hydrogen embrittlement mechanisms": This search will provide information on the mechanisms of hydrogen embrittlement, which are fundamental to understanding hydrogen blistering.
  • "Hydrogen blistering prevention methods": This search will offer resources on strategies for preventing hydrogen blistering in various applications.

Techniques

مصطلحات مشابهة
إدارة سلامة الأصولمعالجة النفط والغازأنظمة إدارة الصحة والسلامة والبيئةالحفر واستكمال الآبار
الأكثر مشاهدة
Categories

Comments


No Comments
POST COMMENT
captcha
إلى