Water Purification

temporary hardness

Temporary Hardness: Understanding and Treating a Common Water Issue

Water hardness is a significant concern in many regions, impacting both domestic and industrial water usage. This article focuses on temporary hardness, a specific type of hardness that can be effectively treated with simple methods.

What is Temporary Hardness?

Temporary hardness refers to the hardness in water caused by the presence of dissolved bicarbonates of calcium and magnesium (Ca(HCO3)2 and Mg(HCO3)2). Unlike permanent hardness, which is caused by sulfates and chlorides of calcium and magnesium, temporary hardness can be removed by boiling.

The Chemistry of Temporary Hardness:

When water containing bicarbonates of calcium and magnesium is heated, the bicarbonates decompose, forming insoluble carbonates of calcium and magnesium. These carbonates precipitate out of the solution as a white, chalky deposit, commonly known as scale.

The chemical reaction involved is:

  • Ca(HCO3)2 (aq) → CaCO3 (s) + H2O (l) + CO2 (g)

The formation of scale is a key indicator of temporary hardness. This scale can cause numerous problems, including:

  • Reduced Water Flow: Scale buildup in pipes and appliances restricts water flow, leading to decreased efficiency.
  • Increased Energy Consumption: Scale build-up in boilers and water heaters decreases their efficiency, requiring more energy to heat water.
  • Damage to Appliances: Scale deposits can damage appliances like kettles, washing machines, and dishwashers.

Treating Temporary Hardness:

Fortunately, temporary hardness is relatively easy to treat. Here are the most common methods:

  • Boiling: As mentioned above, boiling water removes temporary hardness by causing the bicarbonates to decompose and precipitate out as scale.
  • Lime Soda Process: This chemical treatment involves adding lime (Ca(OH)2) and soda ash (Na2CO3) to the water. This process converts the bicarbonates into insoluble carbonates that are then removed by sedimentation and filtration.
  • Ion Exchange: This method uses ion exchange resins to replace the calcium and magnesium ions with sodium ions, effectively softening the water.

Importance of Water Softening:

Treating temporary hardness is crucial for maintaining water quality and efficiency. Soft water not only prevents scale formation, but also:

  • Reduces soap consumption: Hard water reacts with soap to form a soapy scum, requiring more soap for effective cleaning.
  • Improves skin and hair health: Hard water can leave skin feeling dry and itchy, while hair may appear dull and brittle.
  • Protects plumbing and appliances: Soft water prevents scale buildup, extending the lifespan of pipes and appliances.

Conclusion:

Temporary hardness, caused by bicarbonates of calcium and magnesium, poses a significant challenge in many regions. However, with appropriate treatment methods like boiling, lime soda process, and ion exchange, this issue can be effectively managed. By understanding and treating temporary hardness, we can ensure access to clean, soft water for both domestic and industrial applications.


Test Your Knowledge

Quiz: Temporary Hardness

Instructions: Choose the best answer for each question.

1. Which of the following best describes temporary hardness? a) Hardness caused by the presence of dissolved chlorides and sulfates of calcium and magnesium.

Answer

Incorrect. This describes permanent hardness.

b) Hardness caused by the presence of dissolved bicarbonates of calcium and magnesium.
Answer

Correct! This is the definition of temporary hardness.

c) Hardness that cannot be removed by any treatment method.
Answer

Incorrect. Temporary hardness can be treated.

d) Hardness that only occurs in temporary water bodies like ponds and lakes.
Answer

Incorrect. Temporary hardness can occur in any water source.

2. What happens when water containing temporary hardness is boiled? a) The bicarbonates decompose, forming soluble carbonates.

Answer

Incorrect. The carbonates formed are insoluble.

b) The water becomes more acidic.
Answer

Incorrect. Boiling removes temporary hardness, not acidity.

c) The bicarbonates decompose, forming insoluble carbonates that precipitate out as scale.
Answer

Correct! This is the process that removes temporary hardness.

d) The hardness remains unchanged.
Answer

Incorrect. Boiling effectively removes temporary hardness.

3. Which of the following is NOT a problem caused by scale build-up? a) Reduced water flow in pipes and appliances.

Answer

Incorrect. Scale build-up can significantly restrict water flow.

b) Increased energy consumption in water heaters.
Answer

Incorrect. Scale reduces the efficiency of water heaters.

c) Improved skin and hair health.
Answer

Correct! Scale build-up can worsen skin and hair health due to hard water.

d) Damage to appliances like kettles and washing machines.
Answer

Incorrect. Scale can damage appliances by restricting flow and causing malfunctions.

4. Which of the following is a common method for treating temporary hardness? a) Adding chlorine to the water.

Answer

Incorrect. Chlorine is used for disinfection, not hardness removal.

b) The lime soda process.
Answer

Correct! The lime soda process effectively treats temporary hardness.

c) Using a filter to remove suspended particles.
Answer

Incorrect. Filtration doesn't address temporary hardness.

d) Adding vinegar to the water.
Answer

Incorrect. While vinegar can dissolve some scale, it's not a reliable method for treating temporary hardness.

5. What is the main advantage of using soft water? a) It makes water taste better.

Answer

Incorrect. Soft water doesn't necessarily improve taste.

b) It reduces the need for soap and detergents.
Answer

Correct! Soft water doesn't react with soap, reducing consumption.

c) It makes water more acidic.
Answer

Incorrect. Soft water doesn't increase acidity.

d) It increases the effectiveness of chlorine disinfection.
Answer

Incorrect. Soft water doesn't directly impact chlorine disinfection.

Exercise: Temporary Hardness and Scale

Scenario: You've noticed a white, chalky deposit forming on your kettle and the water flow from your showerhead is significantly reduced. You suspect temporary hardness is the culprit.

Task:

  1. Identify two possible solutions for treating the temporary hardness in your water.
  2. Explain how each solution works to remove temporary hardness and prevent scale formation.

Exercise Correction

Here are some possible solutions: **1. Boiling:** * **How it works:** Heating water containing temporary hardness causes the bicarbonates to decompose, forming insoluble carbonates. These carbonates precipitate out as scale, which can be removed by rinsing the kettle or cleaning the showerhead. * **Implementation:** Boil the water in the kettle, then discard the water and clean the kettle with a mild cleaning agent. You can also try boiling the water in a separate container and pouring it through the showerhead to dislodge any scale. **2. Using a Water Softener:** * **How it works:** Water softeners typically use ion exchange resins to replace the calcium and magnesium ions responsible for hardness with sodium ions. This effectively softens the water, preventing further scale formation. * **Implementation:** You'll need to install a water softener system, which may require professional installation depending on your specific needs. These are just two examples. Other solutions may include: * **Lime Soda Process:** This chemical treatment involves adding lime and soda ash to the water. This method is typically used on a larger scale for industrial or municipal water treatment. * **Using a Filter:** While a regular filter won't remove temporary hardness, specialized filters designed to remove calcium and magnesium can be helpful.


Books

  • "Water Treatment: Principles and Design" by C.N. Sawyer, P.L. McCarty, and G.F. Parkin - A comprehensive textbook covering various aspects of water treatment, including hardness and its treatment methods.
  • "Chemistry for Environmental Engineering and Science" by Theodore, J., et al. - This textbook delves into the chemistry of water, including the formation of temporary and permanent hardness and their implications.

Articles

  • "Water Hardness: A Review of Causes, Effects and Treatment Options" - This article provides a comprehensive overview of water hardness, including temporary hardness, its effects, and treatment options. [Search online for this article, available from various sources]
  • "The Chemistry of Water Hardness" - This article explains the chemical processes involved in forming temporary and permanent hardness, providing a detailed understanding of the mechanisms. [Search online for this article, available from various sources]

Online Resources


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