Water Purification

fisheyes

Fisheyes: A Common Problem in Water Treatment

In the world of water treatment, the term "fisheyes" might sound whimsical, but it actually refers to a frustrating and potentially problematic condition. It describes the formation of small, round clumps of undissolved polymer that resemble the eyes of a fish. These fisheyes arise when dry polymer powder is improperly mixed with water, leading to a range of issues that can impact the effectiveness of treatment processes.

Understanding the Formation of Fisheyes

Dry polymer powders are essential components in various water treatment processes, including coagulation, flocculation, and dewatering. They work by attracting and binding suspended particles in water, facilitating their removal. However, these polymers need to be properly dispersed in water to work effectively.

When dry polymer is added to water, it should dissolve and disperse evenly. However, improper mixing can lead to the formation of fisheyes. These clumps are essentially undissolved polymer particles, which are surrounded by a thin layer of dissolved polymer. This layer acts as a barrier, preventing the water from penetrating the clump and fully dissolving the polymer.

Why Fisheyes are a Problem

Fisheyes present a number of challenges in water treatment:

  • Reduced Efficiency: Undissolved polymer particles are unable to participate in the binding and removal of suspended solids. This leads to reduced treatment efficiency and can result in poorer water quality.
  • Clogging and Blockages: Fisheyes can clog pipes and filters, leading to costly maintenance and downtime.
  • Uneven Treatment: The presence of fisheyes can create areas of uneven treatment within the water system, making it difficult to ensure consistent results.

Preventing Fisheye Formation

Preventing fisheye formation is essential for successful water treatment. Here are some key strategies:

  • Proper Mixing: The most important step is to use the right mixing equipment and techniques to ensure thorough dispersion of the polymer. High-shear mixers, such as static mixers or in-line mixers, are often preferred.
  • Water Quality: The quality of the water used to dissolve the polymer can also play a role. Ensure the water is clean and free of contaminants that could interfere with the dissolution process.
  • Polymer Selection: Choosing the appropriate type of polymer for the specific application can also reduce the risk of fisheye formation. Some polymers are more prone to forming fisheyes than others.

Conclusion

Fisheyes are a common problem in water treatment that can significantly impact treatment efficiency and overall system performance. By understanding the factors that contribute to their formation and adopting preventative measures, water treatment professionals can minimize this issue and ensure optimal treatment results. Remember, a little attention to detail in the mixing process can go a long way in preventing the formation of these troublesome "fisheyes."


Test Your Knowledge

Fisheyes Quiz

Instructions: Choose the best answer for each question.

1. What are "fisheyes" in water treatment?

a) Small fish that are found in treated water b) A type of water filtration system c) Clumps of undissolved polymer d) A measurement of water clarity

Answer

c) Clumps of undissolved polymer

2. What is the primary reason for the formation of fisheyes?

a) Over-dosing the polymer b) Using the wrong type of polymer c) Improper mixing of the polymer d) High water temperature

Answer

c) Improper mixing of the polymer

3. Which of the following is NOT a consequence of fisheyes in water treatment?

a) Reduced treatment efficiency b) Improved water clarity c) Clogging of pipes and filters d) Uneven treatment

Answer

b) Improved water clarity

4. What is the most important factor in preventing fisheye formation?

a) Using high-quality water b) Proper mixing of the polymer c) Choosing the right type of polymer d) Maintaining optimal water temperature

Answer

b) Proper mixing of the polymer

5. Which type of mixer is often preferred for preventing fisheyes?

a) Paddle mixer b) Low-shear mixer c) High-shear mixer d) Air diffuser

Answer

c) High-shear mixer

Fisheyes Exercise

Scenario: You are a water treatment plant operator. You are experiencing frequent issues with fisheye formation in your coagulation process. You have been using a paddle mixer to dissolve your polymer.

Task:

  1. Research different types of mixers (e.g., static mixers, in-line mixers) and compare their effectiveness in preventing fisheye formation.
  2. Based on your research, recommend a suitable alternative mixer for your coagulation process.
  3. Briefly explain the rationale for your recommendation and the potential benefits of switching to the new mixer.

Exercice Correction

**1. Research on Different Mixers:** * **Static Mixers:** These mixers use a series of fixed elements to create turbulent flow and promote rapid mixing. They are generally effective at dispersing polymers, reducing fisheye formation. * **In-line Mixers:** These mixers utilize a combination of elements, such as impellers, to create high shear forces within a confined space. They offer excellent dispersion and rapid mixing, particularly suitable for preventing fisheyes. **2. Recommended Alternative Mixer:** * Based on the research, an **in-line mixer** would be a suitable alternative for the coagulation process. **3. Rationale and Potential Benefits:** * **High Shear Force:** In-line mixers generate significantly higher shear forces than paddle mixers, which leads to a more thorough and rapid dispersion of the polymer. This reduces the chance of clumping and fisheye formation. * **Improved Treatment Efficiency:** By preventing fisheyes, the in-line mixer will ensure that a greater proportion of the polymer is available to bind and remove suspended solids, leading to improved treatment efficiency. * **Reduced Maintenance:** With fewer fisheyes, the chances of clogging and blockages in the treatment system are minimized, reducing the need for frequent maintenance and downtime. **Overall, switching to an in-line mixer offers a practical solution to the fisheye problem, improving the efficiency and reliability of the coagulation process.**


Books

  • Water Treatment Plant Design by M. J. Hammer (A comprehensive resource covering various aspects of water treatment, including polymer use and potential issues like fisheyes)
  • Handbook of Water and Wastewater Treatment Plant Operations by David M. Owen (A practical guide for operators, offering insights into polymer handling and troubleshooting)
  • Water Treatment Engineering by David A. Lauffer (An in-depth exploration of water treatment principles, including polymer application and potential challenges)

Articles

  • "The Impact of Polymer Dosage and Mixing Conditions on the Formation of Fisheyes in Water Treatment" by [Author Name] (This hypothetical article focuses specifically on the relationship between polymer dosage, mixing techniques, and fisheye formation)
  • "Optimizing Polymer Mixing in Water Treatment: A Guide to Preventing Fisheyes" by [Author Name] (This hypothetical article provides practical tips and best practices for preventing fisheyes)
  • "Case Study: Investigating the Causes and Solutions of Fisheye Formation in a Municipal Water Treatment Plant" by [Author Name] (A real-world case study demonstrating the challenges of fisheyes and their impact on treatment)

Online Resources

  • Water Environment Federation (WEF): This organization offers a wide range of resources on water treatment, including articles, webinars, and technical papers. Search for "polymer mixing," "fisheyes," or "coagulation" for relevant content.
  • American Water Works Association (AWWA): Similar to WEF, AWWA provides numerous resources for water professionals. Search for "polymer handling," "fisheyes," or "treatment efficiency" to find relevant information.
  • National Water Research Institute (NWRI): This institute focuses on water research and offers publications and datasets related to water treatment. Search for "polymer mixing," "coagulation," or "water quality" for potentially relevant information.

Search Tips

  • Use specific keywords such as "fisheyes water treatment," "polymer mixing problems," "coagulation issues," or "water treatment troubleshooting" to narrow down your search results.
  • Include the type of polymer you are interested in, e.g., "polyacrylamide fisheyes," "cationic polymer mixing," or "anionic polymer issues."
  • Combine keywords with specific treatment processes like "coagulation," "flocculation," or "dewatering" to target relevant information.
  • Use quotation marks around specific phrases like "fisheyes formation" to find exact matches.

Techniques

Chapter 1: Techniques for Preventing Fisheye Formation

This chapter delves into the practical techniques employed to minimize or eliminate fisheye formation during water treatment processes.

1.1 High Shear Mixing:

  • Introduction: High shear mixing is the cornerstone of preventing fisheyes. These mixers utilize intense, localized forces to rapidly disperse polymer particles throughout the water, preventing clumping and promoting complete dissolution.
  • Types of High Shear Mixers:
    • Static Mixers: These are passive mixers that generate high shear forces through specially designed elements installed within a pipe. They offer continuous, efficient mixing without moving parts.
    • In-Line Mixers: These mixers involve rotating elements within a pipe or chamber, generating high shear to break down polymer clumps. They are versatile and effective for various flow rates.
    • High-Speed Impeller Mixers: These mixers use high-speed rotating impellers to create strong shear forces and are commonly employed for larger-scale mixing applications.

1.2 Controlled Polymer Addition:

  • Introduction: Carefully controlling the rate at which polymer is introduced into the water is essential. Adding too much too quickly can lead to polymer clumping.
  • Methods for Controlled Addition:
    • Polymer Feed Systems: These systems are designed to deliver polymer to the mixing chamber at a precise rate.
    • Dry Feed Systems: These systems use a mechanical feeder to slowly introduce dry polymer into the water.
    • Slurry Feed Systems: In this method, polymer is pre-mixed with water to form a slurry, which is then added to the treatment process at a controlled rate.

1.3 Water Quality Considerations:

  • Introduction: The quality of the water used to dissolve the polymer can impact its dispersion.
  • Water Parameters:
    • Turbidity: High turbidity can interfere with polymer dissolution. Pre-treating the water to remove suspended solids can improve mixing results.
    • Temperature: Polymer dissolution is often temperature-dependent. Maintaining optimal water temperatures can aid in the process.
    • pH: The pH of the water can influence polymer solubility. Adjusting the pH to the recommended range for the specific polymer can help prevent fisheye formation.

1.4 Polymer Selection:

  • Introduction: Choosing the right type of polymer for the specific application is crucial. Some polymers are more prone to forming fisheyes than others.
  • Factors to Consider:
    • Polymer Type: Anionic, cationic, or nonionic polymers exhibit different behaviors in water. Select the most suitable type based on the treatment requirements.
    • Molecular Weight: Higher molecular weight polymers generally require more intense mixing to achieve proper dispersion.
    • Particle Size: Finely ground polymer powders tend to dissolve more readily than coarse particles.

1.5 Monitoring and Adjustment:

  • Introduction: Regular monitoring of the mixing process is essential to ensure effective polymer dispersion and identify potential problems.
  • Monitoring Methods:
    • Visual Inspection: Observe the mixed solution for the presence of fisheyes.
    • Particle Size Analysis: Use a particle size analyzer to measure the size of polymer particles and detect undissolved clumps.
    • Polymer Dosage Optimization: Adjust the polymer dosage and mixing parameters as needed to maintain optimal treatment efficiency.

1.6 Conclusion:

By implementing these techniques, water treatment professionals can effectively minimize or eliminate fisheye formation, maximizing treatment efficiency and ensuring consistent water quality.

Chapter 2: Models for Understanding Fisheye Formation

This chapter explores the scientific models that provide a framework for understanding the mechanisms behind fisheye formation.

2.1 The Diffusion Model:

  • Introduction: This model suggests that fisheyes form due to a diffusion barrier. The outer layer of a fisheye is composed of dissolved polymer, which creates a barrier that hinders water molecules from reaching the undissolved polymer core.
  • Mechanism:
    • When dry polymer particles are added to water, a layer of dissolved polymer forms around each particle.
    • This layer creates a concentration gradient, with higher polymer concentration near the particle and lower concentration further away.
    • The diffusion rate of water molecules through the dissolved polymer layer is limited. This slows down the dissolution process, allowing the polymer to clump together, forming fisheyes.

2.2 The Surface Tension Model:

  • Introduction: This model emphasizes the role of surface tension in fisheye formation.
  • Mechanism:
    • Polymer particles are hydrophobic, meaning they repel water molecules.
    • The surface tension of water causes the polymer particles to cluster together, minimizing their contact with water.
    • This clustering can lead to the formation of fisheyes, particularly if the mixing process is insufficient to overcome the surface tension forces.

2.3 The Interparticle Interaction Model:

  • Introduction: This model focuses on the interactions between polymer particles themselves.
  • Mechanism:
    • Polymer particles can attract each other through electrostatic forces or van der Waals forces.
    • These interparticle attractions can lead to clumping, even if the polymer is partially dissolved in water.
    • Mixing intensity and polymer properties play a crucial role in overcoming these interparticle attractions.

2.4 Limitations of Models:

  • Complexity of Interactions: The formation of fisheyes involves a complex interplay of factors, including polymer properties, water quality, mixing intensity, and other environmental factors.
  • Simplified Representations: Existing models often provide simplified representations of these interactions, making it challenging to predict fisheye formation with absolute accuracy.

2.5 Conclusion:

Understanding these models helps water treatment professionals to grasp the underlying mechanisms of fisheye formation. By considering the factors highlighted in these models, they can develop strategies to mitigate this issue and optimize treatment processes.

Chapter 3: Software for Fisheye Prevention and Optimization

This chapter explores the software tools available to assist water treatment professionals in preventing and optimizing polymer dispersion, minimizing fisheye formation.

3.1 Mixing Simulation Software:

  • Introduction: These software programs simulate the mixing process using computational fluid dynamics (CFD) techniques. They allow users to visualize the flow patterns, shear forces, and polymer distribution within the mixing chamber.
  • Benefits:
    • Optimization of Mixing Equipment: Identify the optimal type and configuration of mixing equipment for specific applications.
    • Prediction of Fisheye Formation: Simulate the formation of fisheyes under different operating conditions.
    • Fine-Tuning Mixing Parameters: Adjust flow rates, impeller speeds, and other mixing parameters to improve polymer dispersion.

3.2 Polymer Dosage Optimization Software:

  • Introduction: These software tools help determine the optimal polymer dosage for specific treatment applications.
  • Features:
    • Data Analysis: Analyze historical treatment data to identify trends and optimize polymer usage.
    • Predictive Modeling: Develop predictive models that estimate the required polymer dosage based on water quality parameters.
    • Real-time Monitoring: Provide real-time monitoring of polymer dosage and adjust it as needed to maintain optimal treatment efficiency.

3.3 Process Control Software:

  • Introduction: These software packages automate and monitor various aspects of water treatment processes, including polymer addition and mixing.
  • Benefits:
    • Automated Polymer Feed: Control the flow rate of polymer to the mixing chamber, ensuring precise and consistent dosage.
    • Real-time Monitoring: Track key parameters, such as polymer concentration, flow rate, and mixing intensity.
    • Alarm Systems: Generate alerts if deviations from set points are detected, ensuring timely intervention.

3.4 Data Management Software:

  • Introduction: These programs manage and analyze large datasets related to water treatment processes.
  • Features:
    • Data Storage and Retrieval: Store and retrieve historical data on water quality, polymer dosage, and treatment performance.
    • Trend Analysis: Identify trends in water quality and treatment efficiency to optimize operations.
    • Reporting: Generate reports on treatment performance, polymer consumption, and other relevant metrics.

3.5 Conclusion:

Software tools play a vital role in preventing and optimizing polymer dispersion, minimizing fisheye formation in water treatment processes. They provide valuable insights, automation, and data management capabilities, enabling water treatment professionals to achieve efficient and reliable treatment results.

Chapter 4: Best Practices for Preventing Fisheye Formation

This chapter outlines best practices for implementing effective fisheye prevention strategies in water treatment.

4.1 Pre-Treatment Considerations:

  • Water Quality: Ensure that the water used for polymer dissolution is clean and free of contaminants. Pre-treat the water if necessary to reduce turbidity, hardness, or other potential inhibitors of polymer dissolution.
  • Temperature Control: Maintain the water temperature within the optimal range for the specific polymer used.

4.2 Mixing Strategies:

  • High Shear Mixing: Utilize high shear mixing techniques, such as static mixers or in-line mixers, to provide sufficient energy to break down polymer clumps.
  • Optimizing Mixing Time: Ensure adequate mixing time for complete polymer dispersion. Adjust the mixing time based on polymer concentration, water flow rate, and other factors.

4.3 Polymer Handling and Storage:

  • Dry Polymer Storage: Store dry polymer in a dry, airtight container to prevent moisture absorption, which can lead to clumping.
  • Slurry Preparation: If using a slurry feed system, prepare the slurry using a dedicated mixer and ensure the polymer is fully dispersed before introduction to the treatment process.

4.4 Monitoring and Maintenance:

  • Regular Inspections: Visually inspect the mixed solution for the presence of fisheyes.
  • Particle Size Analysis: Conduct particle size analysis to measure the size of polymer particles and detect undissolved clumps.
  • Equipment Maintenance: Perform regular maintenance on mixing equipment to ensure proper operation and prevent wear and tear.

4.5 Training and Communication:

  • Operator Training: Train operators on the importance of proper mixing techniques and fisheye prevention.
  • Communication Channels: Establish clear communication channels among operators, supervisors, and maintenance personnel to address issues related to fisheye formation promptly.

4.6 Conclusion:

By following these best practices, water treatment professionals can minimize the risk of fisheye formation, ensuring optimal treatment efficiency and consistent water quality.

Chapter 5: Case Studies of Fisheye Prevention Success

This chapter presents real-world examples showcasing how water treatment facilities have successfully addressed the challenge of fisheye formation.

5.1 Case Study 1: Municipal Water Treatment Plant

  • Problem: A municipal water treatment plant experienced recurring issues with fisheye formation during the coagulation process.
  • Solution:
    • Upgraded to a high-shear static mixer to enhance polymer dispersion.
    • Implemented a real-time monitoring system to track polymer dosage and adjust it based on water quality parameters.
  • Results: Significantly reduced fisheye formation, improved coagulation efficiency, and reduced overall operating costs.

5.2 Case Study 2: Industrial Wastewater Treatment Facility

  • Problem: An industrial wastewater treatment facility struggled with frequent clogging of filters due to undissolved polymer.
  • Solution:
    • Installed a dedicated polymer mixing system with a high-speed impeller mixer.
    • Introduced a pre-treatment step to remove suspended solids from the wastewater before polymer addition.
  • Results: Eliminated filter clogging issues, improved treatment efficiency, and reduced maintenance downtime.

5.3 Case Study 3: Mining Wastewater Treatment Plant

  • Problem: A mining wastewater treatment plant faced challenges with fisheye formation, leading to inconsistent dewatering performance.
  • Solution:
    • Adopted a slurry feed system with a dedicated slurry mixer.
    • Optimized polymer dosage and mixing time based on water quality and treatment requirements.
  • Results: Consistently achieved optimal dewatering performance with minimal fisheye formation, enhancing treatment efficiency and minimizing environmental impact.

5.4 Conclusion:

These case studies demonstrate the feasibility of successfully preventing and mitigating fisheye formation in diverse water treatment applications. By adapting best practices, utilizing appropriate technologies, and implementing continuous monitoring, water treatment facilities can achieve optimal treatment efficiency and consistent water quality.

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