Water Purification

degasifier

Degassing: Removing Unwanted Gases from Water and Wastewater

In various industrial and environmental settings, dissolved gases in water can pose significant challenges. These gases, including oxygen, carbon dioxide, hydrogen sulfide, and methane, can lead to corrosion, odor problems, biological growth, and even safety hazards. This is where degasification comes in - a crucial process for removing these dissolved gases from water and wastewater.

The Role of Degassing in Environmental & Water Treatment

Degassing plays a crucial role in various environmental and water treatment applications:

  • Drinking water treatment: Removal of dissolved oxygen prevents corrosion of pipes and improves water taste.
  • Boiler feedwater treatment: Eliminating dissolved oxygen minimizes corrosion in boilers and improves efficiency.
  • Industrial wastewater treatment: Removing dissolved gases like hydrogen sulfide reduces odor and corrosion in industrial processes.
  • Groundwater remediation: Degassing can remove dissolved methane and other volatile organic compounds, protecting groundwater quality.
  • Aquaculture: Removing dissolved oxygen in recirculating aquaculture systems promotes fish health and reduces stress.

The Degassing Process: Stripping Away Unwanted Gases

Degassing is achieved by utilizing the principle of air stripping. This process involves exposing the water to a large surface area of air, allowing the dissolved gases to escape into the atmosphere. The most common type of degasifier is an air stripping column.

Air Stripping Columns: A Key Component of Degassing

Air stripping columns are vertical structures filled with packing material, like plastic rings or saddles. Water flows downward through the column while air is blown upwards. This counter-current flow maximizes contact between the water and air, facilitating the transfer of dissolved gases from the water to the air.

Factors Influencing Degassing Efficiency:

Several factors influence the efficiency of degassing:

  • Temperature: Higher temperatures increase gas solubility, making degassing more effective.
  • Pressure: Lower pressure reduces gas solubility, promoting gas transfer.
  • Contact Time: Longer contact time between water and air enhances gas removal.
  • Surface Area: Greater surface area provided by the packing material increases gas transfer efficiency.

Degassing Technology: Beyond Air Stripping

While air stripping is the most common degassing method, other techniques exist:

  • Vacuum degassing: Applying a vacuum reduces pressure and promotes gas release.
  • Membrane degassing: Utilizing gas-permeable membranes to selectively remove dissolved gases.

Choosing the Right Degassing Method:

Selecting the appropriate degassing method depends on various factors, including the type and concentration of dissolved gases, the required purity level, and the available budget.

Degassing: A Vital Component of Water Treatment

Degassing plays a vital role in ensuring the quality and safety of water and wastewater. By removing unwanted dissolved gases, it protects infrastructure, improves water taste, and safeguards public health. As we strive to achieve sustainable water management, degassing will remain an indispensable tool in the arsenal of water treatment professionals.


Test Your Knowledge

Degassing Quiz

Instructions: Choose the best answer for each question.

1. Which of the following gases is commonly removed during degassing?

a) Nitrogen b) Carbon dioxide c) Helium d) Argon

Answer

b) Carbon dioxide

2. What is the primary principle used in degassing?

a) Filtration b) Oxidation c) Air stripping d) Distillation

Answer

c) Air stripping

3. Which of these factors does NOT influence degassing efficiency?

a) Temperature b) Pressure c) Water color d) Contact time

Answer

c) Water color

4. What is the main component of an air stripping column?

a) Filters b) Pumps c) Packing material d) Heaters

Answer

c) Packing material

5. Which degassing technique utilizes a vacuum to remove gases?

a) Air stripping b) Membrane degassing c) Vacuum degassing d) Chemical degassing

Answer

c) Vacuum degassing

Degassing Exercise

Scenario: You are designing a degassing system for a drinking water treatment plant. The water contains high levels of dissolved oxygen, causing corrosion in the distribution network. You have two options:

  • Option 1: Air stripping column with a large surface area and high air flow rate.
  • Option 2: Vacuum degassing system with a smaller surface area and lower energy consumption.

Task:

  1. Analyze the pros and cons of each option considering factors like efficiency, cost, and energy consumption.
  2. Based on your analysis, recommend which option is more suitable for the drinking water treatment plant and explain your reasoning.

Exercise Correction

**Option 1: Air stripping column** * **Pros:** Highly efficient for removing dissolved oxygen, relatively low cost. * **Cons:** Requires a large surface area, high energy consumption due to air blower. **Option 2: Vacuum degassing system** * **Pros:** Smaller footprint, lower energy consumption. * **Cons:** May be less efficient for removing high levels of dissolved oxygen, higher initial investment. **Recommendation:** Considering the high levels of dissolved oxygen and the need for efficient removal, **Option 1 (air stripping column)** is more suitable. While it requires higher energy consumption, its greater efficiency in removing dissolved oxygen will likely outweigh the higher energy costs in the long run. However, if energy consumption is a major concern, a detailed cost-benefit analysis should be conducted to compare the overall costs of both options, including installation, operation, and maintenance, to make the most informed decision.


Books

  • Water Treatment: Principles and Design by W. Wesley Eckenfelder Jr. and David L. Ford (This comprehensive text covers various aspects of water treatment including degassing)
  • Water Quality and Treatment: A Handbook on Drinking Water by American Water Works Association (AWWA) (A standard reference for water treatment professionals, including sections on degassing)
  • Handbook of Environmental Engineering by Larry A. Brown and James C. DiGioia Jr. (Provides a broad overview of environmental engineering practices, including degassing)
  • Chemical Engineering Handbook by R.H. Perry and D.W. Green (This handbook contains sections on gas-liquid separations and degassing techniques)

Articles

  • "Degassing of Wastewater: A Review" by D.B. Gallagher (This article provides a comprehensive overview of different degassing techniques and their applications)
  • "Air Stripping for the Removal of Volatile Organic Compounds" by R.D. Coughlin and K. Sridharan (Focuses on air stripping for removing volatile organic compounds from water)
  • "Degassing of Water for Industrial Processes: A Review" by R.L. Dickson (This article discusses various degassing methods used in different industrial applications)

Online Resources

  • American Water Works Association (AWWA): https://www.awwa.org/ (Provides technical resources, publications, and standards related to water treatment)
  • Water Environment Federation (WEF): https://www.wef.org/ (Focuses on wastewater treatment technologies and best practices)
  • United States Environmental Protection Agency (EPA): https://www.epa.gov/ (Offers information on water quality standards, regulations, and treatment technologies)

Search Tips

  • Use specific keywords like "degassing," "air stripping," "vacuum degassing," "membrane degassing," and "water treatment."
  • Combine keywords with specific applications like "degassing for drinking water," "degassing for industrial wastewater," or "degassing for aquaculture."
  • Include relevant keywords related to the dissolved gas, such as "oxygen removal," "carbon dioxide removal," or "hydrogen sulfide removal."
  • Use quotation marks to search for exact phrases, for example, "air stripping column."
  • Explore different file types by adding "filetype:pdf" or "filetype:doc" to narrow down your search.

Techniques

Chapter 1: Techniques

Degassing Techniques: Stripping Away Unwanted Gases

Degassing, the process of removing dissolved gases from water and wastewater, utilizes various techniques to achieve this goal. The choice of technique depends on the type and concentration of dissolved gases, the required purity level, and the available budget.

1. Air Stripping:

  • Mechanism: This most common technique involves exposing the water to a large surface area of air, allowing dissolved gases to escape into the atmosphere.
  • Process: The water flows through an air stripping column, a vertical structure filled with packing material like plastic rings or saddles. Air is blown upwards, creating a counter-current flow that maximizes contact between the water and air, facilitating gas transfer.
  • Advantages: Cost-effective, relatively simple to operate, effective for removing volatile gases.
  • Disadvantages: Can be inefficient for removing less volatile gases, requires significant air flow and space.

2. Vacuum Degassing:

  • Mechanism: Applying a vacuum reduces pressure, lowering the solubility of gases and promoting their release.
  • Process: Water is placed in a sealed chamber and a vacuum is applied. The reduced pressure causes dissolved gases to escape from the water into the vacuum space.
  • Advantages: Effective for removing dissolved gases from water with high dissolved gas concentrations, can achieve high purity levels.
  • Disadvantages: Requires specialized equipment, can be energy-intensive, may not be suitable for all applications.

3. Membrane Degassing:

  • Mechanism: Utilizes gas-permeable membranes that selectively remove dissolved gases from water.
  • Process: Water is passed through a membrane that allows gas molecules to pass through but retains water molecules. The permeated gases are collected on the other side of the membrane.
  • Advantages: High efficiency, can remove a wide range of gases, relatively compact and energy-efficient.
  • Disadvantages: Higher initial cost, membrane fouling can occur, requires careful maintenance.

4. Other Techniques:

  • Sonication: Utilizes high-frequency sound waves to promote gas release from solution.
  • Thermal Degassing: Heating the water increases gas solubility and encourages gas release.

Choosing the Right Technique:

The optimal degassing technique depends on the specific application and desired outcome. Careful consideration of factors like gas type, concentration, purity requirements, cost, and available space will guide the selection process.

Chapter 2: Models

Degassing Models: Predicting Gas Removal Efficiency

Mathematical models are essential tools for predicting the efficiency of degassing processes. These models help optimize design parameters, predict gas removal rates, and assess the overall effectiveness of degasification systems.

1. Henry's Law Model:

  • Basis: This model relates the partial pressure of a gas in the gas phase to its concentration in the liquid phase.
  • Application: Widely used to predict gas transfer rates in air stripping and vacuum degassing.
  • Limitations: Assumes ideal gas behavior and neglects potential interactions between dissolved gases.

2. Two-Film Theory Model:

  • Basis: Considers mass transfer across two film layers, one on the liquid side and one on the gas side.
  • Application: Accurately predicts gas transfer rates in air stripping columns, considering factors like liquid and gas flow rates, packing material properties, and mass transfer coefficients.
  • Limitations: Requires detailed information about the specific system and packing material.

3. Computational Fluid Dynamics (CFD) Models:

  • Basis: Utilizes numerical methods to solve the Navier-Stokes equations, simulating the flow and mass transfer within the degasification system.
  • Application: Offers a detailed understanding of the complex fluid dynamics and gas transfer processes within the system, providing insights for optimization.
  • Limitations: Requires significant computational resources and expertise in CFD modeling.

Model Selection:

The choice of degassing model depends on the desired level of detail and accuracy. Simple models like Henry's Law are suitable for preliminary estimations, while more complex models like the two-film theory or CFD models offer detailed analysis and optimization capabilities.

Chapter 3: Software

Degassing Software: Streamlining Design and Analysis

Specialized software tools can simplify the design, analysis, and optimization of degassing systems. These software packages provide integrated tools for:

1. Design and Simulation:

  • Process simulation: Simulating the behavior of the degassing system under different operating conditions.
  • Equipment sizing: Determining optimal dimensions for air stripping columns, vacuum chambers, and membrane systems.
  • Packing selection: Evaluating different packing materials for air stripping columns based on gas transfer efficiency and pressure drop.

2. Data Analysis:

  • Gas removal calculations: Calculating gas removal rates and efficiencies based on experimental data.
  • Economic evaluation: Performing cost-benefit analysis for different degassing options.
  • Environmental impact assessment: Evaluating the potential environmental impacts of degassing processes.

3. Optimization:

  • Process optimization: Adjusting operating parameters to maximize gas removal efficiency and minimize costs.
  • Control system design: Developing control strategies for automated degassing processes.
  • Integration with other systems: Connecting degassing systems with other water treatment processes.

Software Examples:

  • Aspen Plus: Process simulation software for design and optimization of degassing systems.
  • COMSOL Multiphysics: CFD software for detailed analysis of fluid flow and mass transfer within degasification systems.
  • ChemCAD: Process simulation software for evaluating the performance of various degassing technologies.

Benefits of Software:

Degassing software offers numerous benefits, including:

  • Increased accuracy: Providing precise predictions for gas removal rates and efficiency.
  • Reduced design time: Streamlining the design and optimization process.
  • Improved decision-making: Providing data-driven insights for informed decision-making.
  • Enhanced operational efficiency: Optimizing degassing systems for improved performance and reduced costs.

Chapter 4: Best Practices

Degassing Best Practices: Ensuring Efficient and Effective Gas Removal

Optimizing degassing processes requires adherence to best practices to ensure efficient and effective gas removal, protect equipment, and minimize environmental impact.

1. Design Considerations:

  • Adequate surface area: Ensure sufficient packing material in air stripping columns to maximize gas transfer.
  • Proper air flow: Provide sufficient air flow to ensure complete gas removal from the water.
  • Optimal liquid flow rate: Maintain an appropriate liquid flow rate to ensure adequate contact time with air.
  • Effective packing selection: Choose packing materials that maximize surface area, minimize pressure drop, and resist fouling.
  • Vacuum degassing: Select appropriate vacuum pumps and ensure proper vacuum seal for optimal gas removal.
  • Membrane degassing: Choose membranes with high gas permeabilities and ensure adequate membrane surface area.

2. Operational Practices:

  • Regular maintenance: Maintain the degassing system regularly to prevent fouling and ensure proper functioning.
  • Monitor operating parameters: Track air flow, liquid flow rate, pressure, and temperature to identify potential issues.
  • Optimize gas removal: Adjust operating parameters to maximize gas removal efficiency and minimize energy consumption.
  • Safety precautions: Implement safety protocols to prevent accidents and ensure proper handling of chemicals.
  • Environmental considerations: Minimize air emissions and dispose of waste products responsibly.

3. Troubleshooting:

  • Reduced gas removal: Investigate factors like insufficient air flow, fouling, or incorrect operating conditions.
  • Increased pressure drop: Check for packing material degradation, air flow blockage, or inadequate packing selection.
  • Equipment failure: Inspect and maintain vacuum pumps, membranes, and other equipment regularly.

4. Ongoing Optimization:

  • Performance monitoring: Continuously monitor gas removal efficiency and identify areas for improvement.
  • Data analysis: Analyze operating data to identify patterns and trends that can be used for optimization.
  • Regular maintenance: Implement preventive maintenance schedules to ensure optimal performance.

By adhering to these best practices, you can ensure efficient and effective degassing, achieving optimal gas removal while minimizing costs and environmental impact.

Chapter 5: Case Studies

Degassing in Action: Real-World Applications and Success Stories

Degassing technology plays a vital role in various industries, from drinking water treatment to industrial wastewater management. These case studies demonstrate the effectiveness of degassing in addressing specific challenges and achieving desired outcomes.

1. Drinking Water Treatment:

  • Challenge: Removing dissolved oxygen from drinking water to prevent corrosion and improve taste.
  • Solution: Air stripping is used to remove dissolved oxygen from the water, resulting in improved water quality and reduced corrosion in distribution systems.
  • Outcome: Enhanced water quality and reduced maintenance costs for water treatment facilities.

2. Boiler Feedwater Treatment:

  • Challenge: Eliminating dissolved oxygen from boiler feedwater to prevent corrosion and improve efficiency.
  • Solution: Vacuum degassing is employed to remove dissolved oxygen, preventing costly boiler failures and downtime.
  • Outcome: Increased boiler lifespan, improved efficiency, and reduced maintenance expenses.

3. Industrial Wastewater Treatment:

  • Challenge: Removing dissolved hydrogen sulfide from industrial wastewater to reduce odor and corrosion.
  • Solution: Air stripping is used to remove hydrogen sulfide, mitigating odor issues and protecting industrial equipment.
  • Outcome: Improved working conditions, reduced environmental impact, and cost savings associated with corrosion control.

4. Groundwater Remediation:

  • Challenge: Removing dissolved methane and volatile organic compounds from contaminated groundwater.
  • Solution: Air stripping or vacuum degassing is employed to remove these contaminants, restoring groundwater quality.
  • Outcome: Protecting groundwater resources, ensuring safe water supply, and promoting environmental sustainability.

5. Aquaculture:

  • Challenge: Removing dissolved oxygen from recirculating aquaculture systems to promote fish health and reduce stress.
  • Solution: Specialized degassing systems are used to control oxygen levels, promoting fish growth and maximizing aquaculture productivity.
  • Outcome: Improved fish health, reduced mortality rates, and increased yield in aquaculture operations.

These case studies highlight the versatility and effectiveness of degassing technology in addressing various challenges related to dissolved gases in water and wastewater. By understanding the principles of degassing, selecting appropriate techniques, and implementing best practices, industries can effectively remove unwanted gases, improve water quality, and protect environmental resources.

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