Purification de l'eau

stripper

Le Stripping : Un Outil Puissant pour l'Eau Propre

Le stripping est une technologie largement utilisée dans le traitement environnemental et de l'eau, employée pour éliminer les contaminants volatils et semi-volatils de l'eau. Ce procédé repose sur le principe du **transfert de masse**, où les contaminants sont transférés de la phase liquide (eau) à la phase gazeuse (air).

Fonctionnement du Stripping :

Le principe de base du stripping est simple. L'eau contaminée est mise en contact avec un flux gazeux (généralement de l'air) qui a une concentration plus faible du contaminant. En raison de la différence de concentration, le contaminant se vaporise de l'eau et se dissout dans l'air. Ce processus est régi par la **Loi de Henry**, qui stipule que la solubilité d'un gaz dans un liquide est proportionnelle à la pression partielle du gaz au-dessus du liquide.

Composants clés d'un système de stripping :

  1. Colonne de stripping : Il s'agit du composant central du système où le transfert réel des contaminants a lieu. La colonne est généralement remplie de matériau d'emballage (comme des anneaux en plastique ou en céramique) pour augmenter la surface de contact entre l'eau et le gaz.
  2. Alimentation en air : Un souffleur ou un compresseur fournit le flux d'air utilisé pour extraire les contaminants de l'eau.
  3. Entrée et sortie liquides : Ces connexions permettent à l'eau contaminée d'entrer dans la colonne de stripping et à l'eau traitée de sortir.
  4. Entrée et sortie de gaz : Ces connexions permettent au flux d'air d'entrer et de sortir de la colonne, transportant les contaminants extraits.

Types de stripping :

  • Stripping à l'air : Le type le plus courant, utilisant l'air comme gaz de stripping.
  • Stripping à la vapeur : Utilise la vapeur comme gaz de stripping, efficace pour éliminer les contaminants plus volatils.
  • Stripping sous vide : Réduit la pression dans la colonne, ce qui augmente la pression de vapeur des contaminants, facilitant leur élimination.

Applications du stripping dans le traitement de l'eau :

  • Élimination des composés organiques volatils (COV) : Le stripping est très efficace pour éliminer les COV tels que le trichloroéthylène (TCE), le tétrachloroéthylène (PCE) et le benzène.
  • Élimination du sulfure d'hydrogène (H2S) : Le stripping est utilisé pour éliminer le H2S de l'eau, qui peut causer des odeurs désagréables et de la corrosion.
  • Élimination de l'ammoniac : Le stripping peut être utilisé pour éliminer l'ammoniac des eaux usées, en particulier dans le traitement des effluents industriels.

Avantages du stripping :

  • Efficacité : Le stripping est un processus très efficace pour éliminer les contaminants volatils et semi-volatils.
  • Rentabilité : Comparé à d'autres méthodes de traitement, le stripping peut être une solution rentable.
  • Relativement simple : La technologie de stripping est relativement simple à utiliser et à entretenir.

Limites du stripping :

  • Pas efficace pour tous les contaminants : Le stripping est principalement efficace pour les composés volatils et semi-volatils. Il n'est pas adapté à l'élimination des contaminants non volatils ou des contaminants ayant une faible pression de vapeur.
  • Risque d'émissions atmosphériques : Le stripping peut libérer des contaminants dans l'air, ce qui nécessite des mesures de contrôle appropriées pour atténuer les impacts environnementaux potentiels.

Conclusion :

Le stripping est un outil précieux dans le traitement environnemental et de l'eau, éliminant efficacement une large gamme de contaminants volatils et semi-volatils de l'eau. Comprendre ses principes et ses limites est crucial pour une mise en œuvre réussie et l'optimisation des résultats du traitement pour des ressources en eau plus propres et plus sûres.


Test Your Knowledge

Quiz: Stripping: A Powerful Tool for Clean Water

Instructions: Choose the best answer for each question.

1. What is the primary principle behind stripping technology?

a) Adsorption

Answer

Incorrect. Adsorption involves the attachment of contaminants to a solid surface.

b) Oxidation

Answer

Incorrect. Oxidation involves the addition of oxygen to a compound.

c) Mass transfer

Answer

Correct! Stripping relies on the transfer of contaminants from the liquid to the gas phase.

d) Chemical precipitation

Answer

Incorrect. Chemical precipitation involves forming solid particles from dissolved substances.

2. Which law governs the solubility of a gas in a liquid during stripping?

a) Dalton's Law

Answer

Incorrect. Dalton's Law deals with partial pressures of gases in a mixture.

b) Henry's Law

Answer

Correct! Henry's Law describes the relationship between gas solubility and partial pressure.

c) Boyle's Law

Answer

Incorrect. Boyle's Law relates pressure and volume of a gas.

d) Charles' Law

Answer

Incorrect. Charles' Law relates volume and temperature of a gas.

3. What is the primary function of packing material in a stripping column?

a) To filter out solid particles

Answer

Incorrect. Filtration is not the primary function of packing material in stripping.

b) To increase the contact area between water and gas

Answer

Correct! The packing increases surface area for efficient mass transfer.

c) To prevent backflow of air

Answer

Incorrect. Backflow prevention is usually handled by other system components.

d) To absorb contaminants

Answer

Incorrect. Stripping does not rely on absorption, but rather on vaporization.

4. Which type of stripping is most commonly used in water treatment?

a) Vacuum stripping

Answer

Incorrect. Vacuum stripping is less common than air stripping.

b) Steam stripping

Answer

Incorrect. Steam stripping is effective but less common than air stripping.

c) Air stripping

Answer

Correct! Air stripping is the most widely used method due to its simplicity and effectiveness.

d) Ozone stripping

Answer

Incorrect. Ozone is used for oxidation, not stripping.

5. What is a potential limitation of stripping technology?

a) It is not effective for removing volatile compounds

Answer

Incorrect. Stripping is specifically effective for volatile compounds.

b) It is expensive compared to other treatment methods

Answer

Incorrect. Stripping is often considered a cost-effective solution.

c) It can potentially release contaminants into the air

Answer

Correct! Proper control measures are needed to mitigate air emissions.

d) It requires complex and specialized equipment

Answer

Incorrect. Stripping technology is relatively simple to operate and maintain.

Exercise: Designing a Stripping System

Task: A small industrial plant discharges wastewater containing 10 ppm of TCE (trichloroethylene). Design a basic stripping system to remove the TCE from the wastewater. Consider the following:

  1. Stripping Column: Choose a suitable packing material and estimate the column height required for achieving a desired TCE removal efficiency (e.g., 90%).
  2. Air Supply: Determine the air flow rate needed to ensure effective stripping.
  3. Control Measures: Propose measures to minimize potential air emissions of TCE.

Exercice Correction

This exercise requires further research and calculations. Here's a general approach:

1. Stripping Column:

  • Packing Material: Common options include plastic or ceramic rings, saddles, or Pall rings. The specific choice depends on factors like TCE concentration, desired efficiency, and available space.
  • Column Height: This is determined by the mass transfer rate and the required contact time between the wastewater and air. The Henry's Law constant for TCE and the desired removal efficiency will help calculate the required height.
  • Additional Considerations: Factors like wastewater flow rate, temperature, and pressure also influence column design.

2. Air Supply:

  • Air Flow Rate: The required air flow rate is related to the wastewater flow rate and the mass transfer coefficient for TCE. Higher flow rates can lead to more efficient stripping.

3. Control Measures:

  • Air Emission Control: Options include:
    • Activated Carbon Adsorption: Capturing TCE before releasing the air into the atmosphere.
    • Condensation: Cooling the air stream to condense and capture TCE.
    • Catalytic Oxidation: Converting TCE into less harmful products.

Note: A complete design requires detailed calculations and simulations, but this exercise aims to illustrate the general considerations involved in designing a stripping system.


Books

  • Water Treatment: Principles and Design by W. Wesley Eckenfelder Jr. and David B. Benefield (This classic covers various water treatment methods, including stripping)
  • Environmental Engineering: A Global Text by C.H.S. Davie, D.G. Linton, and H.R. Hemmings (Covers the fundamentals of environmental engineering, including stripping in wastewater treatment)
  • Handbook of Environmental Engineering edited by L. Theodore (Offers a broader overview of environmental engineering, including sections on stripping and air pollution control)

Articles

  • "Air Stripping for the Removal of Volatile Organic Compounds from Water" by P. C. Singer and R. D. Letterman (A detailed study on the theory and applications of air stripping for VOC removal)
  • "Stripping Technology for the Removal of Volatile Organic Compounds from Wastewater" by T. H. Adams and R. W. Grady Jr. (A comprehensive review of stripping techniques for VOCs in wastewater treatment)
  • "Removal of Ammonia from Wastewater by Air Stripping: A Review" by Y. Yang, J. Zhang, and Y. Li (Focuses specifically on ammonia removal using air stripping in wastewater treatment)

Online Resources

  • US EPA's Tech fact Sheet: Air Stripping (Provides a concise overview of air stripping, including its applications, limitations, and design considerations)
  • Water Environment Federation (WEF): Stripping (A technical resource from WEF, offering information on stripping processes, best practices, and industry standards)
  • USEPA’s Technology Innovation and Field Demonstration (TIFD) Program: Air Stripping (Offers practical guidance on air stripping technology for specific applications and scenarios)

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