Glossary of Technical Terms Used in Water Purification: reactivity

reactivity

Reactivity in Environmental & Water Treatment: The Power of Chemical Change

Reactivity, the tendency of a chemical substance to readily engage in chemical reactions with other elements and compounds, plays a crucial role in environmental and water treatment. Understanding and controlling reactivity allows us to address various environmental challenges, from cleaning up pollutants to purifying water for consumption.

1. Pollutant Removal & Degradation:

  • Oxidation: Reactive chemicals like ozone (O3) and chlorine (Cl2) are potent oxidizers used to break down organic pollutants and kill bacteria in wastewater. Ozone's high reactivity oxidizes a wide range of contaminants, including pesticides, pharmaceuticals, and disinfection byproducts. Chlorine, though less reactive than ozone, remains effective for disinfection and organic matter removal.
  • Reduction: Reactive metals like iron (Fe) and aluminum (Al) are used to remove heavy metals and other contaminants through reduction reactions. These metals bind to contaminants, removing them from the water.
  • Catalysis: Certain reactive materials act as catalysts, speeding up chemical reactions without being consumed themselves. This is utilized in various processes like the catalytic oxidation of volatile organic compounds (VOCs) in air pollution control.

2. Water Treatment & Purification:

  • Coagulation & Flocculation: Aluminum and iron salts are used to remove suspended particles and turbidity from water. These salts react with water, forming reactive hydroxides that attract and bind suspended matter, forming flocs that are easily removed.
  • Disinfection: Chlorine, ozone, and ultraviolet (UV) radiation are employed to eliminate harmful microorganisms in water. Chlorine reacts with microorganisms, disrupting their cellular functions and causing their death. Ozone, due to its high reactivity, is a powerful disinfectant and can also oxidize organic matter. UV radiation disrupts the DNA of microorganisms, rendering them inactive.

3. Soil & Groundwater Remediation:

  • Bioremediation: Reactive microorganisms are used to break down pollutants in soil and groundwater. These organisms use pollutants as food sources, converting them into less harmful substances.
  • Chemical Reduction & Oxidation: In situ chemical reduction or oxidation techniques utilize reactive chemicals to immobilize or degrade contaminants in soil and groundwater. For example, iron nanoparticles can be used to reduce toxic metals like arsenic to less harmful forms.

Challenges and Considerations:

  • Selectivity: While reactivity is essential for treatment processes, it also poses challenges. High reactivity can lead to undesirable side reactions, generating unintended byproducts or damaging equipment.
  • Safety: Handling reactive chemicals requires specialized equipment and training to ensure worker safety and environmental protection.
  • Cost: The cost of reactive chemicals, their application, and potential waste disposal can be significant.

Moving Forward:

Understanding and controlling reactivity are crucial for effective environmental and water treatment. As technology advances, research into novel, highly selective and safe reactive materials continues, aiming to enhance existing treatments and develop sustainable solutions to address global environmental challenges.


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