Glossary of Technical Terms Used in Water Purification: available chlorine

available chlorine

Available Chlorine: The Powerhouse of Water Disinfection

In the realm of environmental and water treatment, chlorine stands as a crucial weapon against harmful microorganisms. However, not all chlorine sources are created equal. This is where the concept of available chlorine comes into play, a critical measure that determines the effectiveness of chlorine-based disinfectants.

What is Available Chlorine?

Available chlorine represents the amount of active chlorine present in a substance, expressed as a percentage. It reflects the chlorine's potential to oxidize and disinfect compared to pure chlorine gas or liquid chlorine.

Think of it as a measure of how much "punch" a chlorine source has. The higher the available chlorine, the stronger the disinfecting power.

Why is Available Chlorine Important?

  • Accurate Dosing: Available chlorine allows for precise calculations when using chlorine-based disinfectants. Knowing the available chlorine content helps determine the appropriate dosage to achieve the desired disinfection level.
  • Choosing the Right Source: Different chlorine sources have varying available chlorine percentages. For example, calcium hypochlorite (bleach) typically has an available chlorine content around 65%, while sodium hypochlorite solution can range from 10% to 15%.
  • Effective Disinfection: The available chlorine content directly impacts the effectiveness of the disinfectant. Higher available chlorine means faster and more potent disinfection, ensuring the elimination of harmful pathogens in water treatment processes.

Common Chlorine Sources and Their Available Chlorine:

  • Liquid Chlorine: 100% available chlorine
  • Chlorine Gas: 100% available chlorine
  • Calcium Hypochlorite (Bleach): 65% available chlorine
  • Sodium Hypochlorite: 10-15% available chlorine
  • Chlorine Dioxide: 100% available chlorine

Applications of Available Chlorine:

  • Water Treatment: Disinfecting drinking water, swimming pools, and wastewater.
  • Industrial Processes: Sanitizing equipment, sterilizing surfaces, and bleaching fabrics.
  • Agriculture: Controlling pests and diseases in crops and livestock.

Understanding Available Chlorine: Key Points to Remember:

  • It's not about the total chlorine content, but the active chlorine that can oxidize and disinfect.
  • Higher available chlorine means a more potent disinfectant.
  • The available chlorine content varies between different chlorine sources.
  • Always check the available chlorine percentage on product labels.

By understanding the concept of available chlorine, water treatment professionals and other users of chlorine-based disinfectants can make informed decisions to ensure effective sanitation and disinfection practices. This knowledge contributes to a healthier environment and safer water for all.


Test Your Knowledge

Available Chlorine Quiz:

Instructions: Choose the best answer for each question.

1. What does "available chlorine" represent?

a) The total amount of chlorine in a substance. b) The amount of active chlorine that can oxidize and disinfect. c) The concentration of chlorine in a solution. d) The weight of chlorine in a substance.

Answer

b) The amount of active chlorine that can oxidize and disinfect.

2. Why is available chlorine important in water treatment?

a) It helps determine the pH of the water. b) It allows for accurate dosing of chlorine-based disinfectants. c) It measures the turbidity of the water. d) It helps remove heavy metals from water.

Answer

b) It allows for accurate dosing of chlorine-based disinfectants.

3. Which of the following chlorine sources has the highest available chlorine content?

a) Sodium hypochlorite (bleach) b) Calcium hypochlorite (bleach) c) Chlorine gas d) Chlorine dioxide

Answer

c) Chlorine gas

4. What is the typical available chlorine content of calcium hypochlorite (bleach)?

a) 10% b) 15% c) 65% d) 100%

Answer

c) 65%

5. How does the available chlorine content affect disinfection effectiveness?

a) Higher available chlorine means slower disinfection. b) Higher available chlorine means weaker disinfection. c) Higher available chlorine means faster and more potent disinfection. d) Available chlorine has no effect on disinfection effectiveness.

Answer

c) Higher available chlorine means faster and more potent disinfection.

Available Chlorine Exercise:

Scenario: You need to disinfect a swimming pool with a volume of 50,000 gallons. The desired chlorine concentration is 1 ppm (part per million). You have access to calcium hypochlorite (bleach) with an available chlorine content of 65%.

Task:

  1. Calculate the amount of calcium hypochlorite needed to achieve the desired chlorine concentration.
  2. Explain how you arrived at your answer.

Exercice Correction

1. Calculation: * **Desired chlorine concentration:** 1 ppm * **Pool volume:** 50,000 gallons * **Available chlorine in calcium hypochlorite:** 65% * **Step 1:** Calculate the total chlorine needed: 1 ppm * 50,000 gallons = 50,000 ppm-gallons * **Step 2:** Convert ppm-gallons to pounds of chlorine: 50,000 ppm-gallons * 8.34 lbs/1,000,000 ppm-gallons = 0.417 lbs of chlorine * **Step 3:** Calculate the amount of calcium hypochlorite needed: 0.417 lbs of chlorine / 0.65 (available chlorine) = 0.64 lbs of calcium hypochlorite 2. Explanation: We first calculated the total amount of chlorine needed for the desired concentration in the pool. Then, we converted this value into pounds of chlorine. Finally, we divided the required amount of chlorine by the available chlorine content in calcium hypochlorite to determine the necessary weight of the bleach.


Books

  • Water Treatment: Principles and Design by AWWA (American Water Works Association)
  • Chemistry for Environmental Engineering and Science by Clair N. Sawyer, Perry L. McCarty, and Gene F. Parkin
  • Handbook of Water and Wastewater Treatment Plant Operations by David A. Cornwell

Articles

  • "Chlorine Disinfection: A Review" by A. K. Singh and D. K. Singh (International Journal of Environmental Science and Technology)
  • "The Chemistry of Chlorine Disinfection" by John C. Hoff (Water Environment Research)
  • "Available Chlorine: A Critical Parameter in Water Disinfection" by K. R. Srinivasan (Journal of Environmental Protection)

Online Resources

  • United States Environmental Protection Agency (EPA): https://www.epa.gov/ (Search for "chlorine disinfection" or "available chlorine")
  • Water Quality & Treatment: The Fifth Edition: https://www.awwa.org/ (Comprehensive resource on water treatment, including chlorine disinfection)
  • The Chlorine Institute: https://www.chlorineinstitute.org/ (Information on chlorine chemistry, safety, and applications)

Search Tips

  • Use specific keywords: "available chlorine," "chlorine disinfection," "chlorine chemistry," "chlorine dosage."
  • Combine keywords with search operators: "available chlorine" + "water treatment" OR "available chlorine" + "swimming pools"
  • Use advanced search operators: "site:epa.gov available chlorine" OR "filetype:pdf available chlorine"
Similar Terms
Water Purification
Wastewater Treatment
Environmental Health & Safety
Air Quality Management
Sustainable Water Management
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